When we think of electricity, we don’t usually think of charged particles pushing and pulling on each other, mediated by vector fields. Usually we think of electrons flowing along wires. But what makes them flow?
The answer is summed up in something that is named — very confusingly — “electromotive force”. The word “force” is just a word here, so try to keep from thinking of it as a force. In fact, it’s more analogous to work, in the same way the electric field is analogous to force.
We calculate the work done by a force in moving a particle along a path is given by the line integral
If is conservative, this amounts to the difference in “potential energy” between the start and end of the path. We often interpret a work integral as an energy difference even in a more general setting. Colloquially, we sometimes say that particles “want to move” from high-energy states to low-energy ones.
Similarly, we define the electromotive force along a path to be the line integral
If the electric field is conservative — the gradient of some potential function — then the electromotive force over a path is the difference between the potential at the end and at the start of the path. But, we may ask, why the negative sign? Well, it’s conventional, but I like to think of it in terms of electrons, which have negative charge; given electric field “pushes” an electron in the opposite direction, thus we should take the negative to point the other way.
In any event, just like the electric field measures force per unit of charge, electromotive force measures work per unit of charge, and is measured in units of energy per unit of charge. In the SI system, there is is a unit called a volt — with symbol — which is given by
And often electromotive force is called “voltage”. For example, a battery — through chemical processes — induces a certain difference in the electric potential between its two terminals. In a nine-volt battery this difference is, predictably enough, , and the same difference is induced along the path of a wire leading from one terminal, through some electric appliance, and back to the other terminal. Just like the potential energy difference “pushes” particles along from high-energy states to low-energy ones, so the voltage difference “pushes” charged particles along the wire.